Research and Development of Online Monitoring Protection Sensors for Paper Books Based on TiO2 NT/MoS2

NO2 is a prevalent environmental pollutant, and its reaction with water produces nitric acid, which is one of the main factors contributing to the degradation of books and paper. Therefore, it is crucial to develop a real-time monitoring system for NO2 gas content in the air and establish timely response measures to delay book aging and provide effective protection. In this study, TiO2 nanotubes (NTs) were fabricated using the anodic oxidation method, followed by the preparation of TiO2 NT/MoS2 composites through hydrothermal synthesis. It was observed that flaky MoS2 is attached to the surface of TiO2 nanotubes, forming aggregated structures resembling flower balls. The TiO2 NT/MoS2 nanocomposites were found to exhibit a rapid response with a 5 s response time and an 80 s recovery time towards 367 ppm NO2 at 260 °C. The gas response to 100 ppm NO2 vapor was 3.3, which is higher than all the other gases under the same concentration. Our experimental results demonstrate that compared to pure TiO2 NTs, TiO2 NT/MoS2 composites exhibit a larger specific surface area along with higher sensitivity and faster response times towards various concentrations of NO2 gas.