Intermolecular Amine Transfer to Enantioenriched trans-3-Phenylglycidates by an α/β-Aminomutase to Access Both anti-Phenylserine Isomers
ACS Catalysis（2020）
摘要
β-Hydroxy-α-amino acids are noncanonical amino acids with two stereocenters and with useful applications in the pharmaceutical and agrochemical sectors. Here, a 5-methylidene-3,5-dihydro-4H-imidazo...
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关键词
biocatalysis, enzyme catalysis, MIO-aminomutase, 3-phenylglycidate, cinnamate epoxide, phenylserine, phenylisoserine, beta-hydroxy-alpha-amino acids
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