Oxidation of Alcohols with 1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane Chlorochromate (BAAOCC) under Nonaqueous Conditions.

Abdol R. Hajipour,Hamid R. Bagheri,Arnold E. Ruoho

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY（2005）

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摘要

1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane chlorochromate (BAAOC) in the presence of AlCl3 affords an efficient and mild system for oxidation of a variety of alcohols, giving the corresponding aldehydes and ketones in refluxing acetonitrile. The experimental procedure is simple and the products are isolated straightforward in good to excellent yields.

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关键词

dehydrogenation,oxidation

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